Uranium–Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex

Author(s)
Fox, Alexander R.; Cummins, Christopher C.
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Abstract
While uranium imido complexes are well established in the literature, complexes featuring a uranium nitride functionality are rare. Data pertaining to terminal uranium nitrides are limited to the spectroscopic observation of the binary uranium nitrides UN and NUN and the ternary nitride NUF[subscript 3] under matrix conditions. We are interested in the uranium nitride functional group as it incorporates metal-ligand multiple bonding, valence f orbitals, and redox activity.
Date issued
2008-12
URI
http://hdl.handle.net/1721.1/64734
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society
Citation
Fox, Alexander R., and Christopher C. Cummins. “Uranium−Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex.” Journal of the American Chemical Society 131.16 (2009) : 5716-5717.
Version: Author's final manuscript
ISSN
0002-7863
1520-5126
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