| dc.contributor.author | Cossairt, Brandi M. | |
| dc.contributor.author | Cummins, Christopher C. | |
| dc.date.accessioned | 2011-12-14T14:27:46Z | |
| dc.date.available | 2011-12-14T14:27:46Z | |
| dc.date.issued | 2010-04 | |
| dc.date.submitted | 2010-02 | |
| dc.identifier.issn | 1144-0546 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/67661 | |
| dc.description.abstract | A reaction scheme has been devised according to 3 RX + 3 Ti(III) + 0.25 P₄ → PR₃ + 3 XTi(IV), wherein RX = PhBr, CyBr, Me₃SiI or Ph₃SnCl, with contrasting results in the case of more hindered RX. The scheme accomplishes the direct radical functionalization of white phosphorus without the intermediacy of PCl₃. | en_US |
| dc.language.iso | en_US | |
| dc.publisher | RSC Publishing | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1039/c0nj00124d | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
| dc.source | Prof. Cummins | en_US |
| dc.title | Radical synthesis of trialkyl, triaryl, trisilyl and tristannyl phosphines from P₄ | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Cossairt, Brandi M., and Christopher C. Cummins. “Radical Synthesis of Trialkyl, Triaryl, Trisilyl and Tristannyl Phosphines from P4.” New Journal of Chemistry 34.8 (2010) : 1533. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Cummins, Christopher C. | |
| dc.contributor.mitauthor | Cummins, Christopher C. | |
| dc.contributor.mitauthor | Cossairt, Brandi M. | |
| dc.relation.journal | New Journal of Chemistry | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Cossairt, Brandi M.; Cummins, Christopher C. | en |
| dc.identifier.orcid | https://orcid.org/0000-0003-2568-3269 | |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
