Carbanionic Route to Electroactive Carbon-Centered Anion and Radical Oligomers

Author(s)
Dane, Eric L.; Swager, Timothy Manning
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Abstract
The synthesis of poly-1,3-bisdiphenylene-2-phenyl allyl (BDPA) radicals via a new anionic oligomerization strategy is reported. The material displays a reversible reduction from the orange-red radical to the blue carbanion in solution.
Description
Experimental details and additional spectra are available free of charge via the Internet at http://pubs.acs.org.
Date issued
2010-09
URI
http://hdl.handle.net/1721.1/67695
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Organic Letters
Publisher
American Chemical Society
Citation
Dane, Eric L., and Timothy M. Swager. “Carbanionic Route to Electroactive Carbon-Centered Anion and Radical Oligomers.” Organic Letters 12 (2010): 4324-4327. Web. 15 Dec. 2011. © 2011 American Chemical Society
Version: Author's final manuscript
ISSN
1523-7060
1523-7052
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