Chemistry of Nitrosyliron Complexes Supported by a beta-Diketiminate Ligand

Author(s)
Tonzetich, Zachary J.; Heroguel, Florent; Do, Loi Hung; Lippard, Stephen J.
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Chemistry of Nitrosyliron Complexes Supported by a β-Diketiminate Ligand
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Abstract
Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6-diisopropylphenyl)NC(Me)]2CH). The dinitrosyliron complexes [Fe(NO)2(Ar-nacnac)] (1) and (Bu4N)[Fe(NO)2(Ar-nacnac)] (2) react with [FeIII(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [FeII(NO)(TPP)] and the corresponding mononitrosyliron complexes. The factors governing NO transfer with dinitrosyliron complexes (DNICs) 1 and 2 are evaluated, together with the chemistry of the related mononitrosyliron complex, [Fe(NO)Br(Ar-nacnac)] (4). The synthesis and properties of the related cobalt dinitrosyl [Co(NO)2(Ar-nacnac)] (3) is also discussed for comparison to DNICs 1 and 2. The solid-state structures of several of these compounds as determined by X-ray crystallography are reported.
Date issued
2011-01
URI
http://hdl.handle.net/1721.1/69074
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Inorganic Chemistry
Publisher
American Chemical Society
Citation
Tonzetich, Zachary J. et al. “Chemistry of Nitrosyliron Complexes Supported by a β-Diketiminate Ligand.” Inorganic Chemistry 50.4 (2011): 1570-1579.
Version: Author's final manuscript
ISSN
0020-1669
1520-510X
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