| dc.contributor.author | Flook, Margaret M. | |
| dc.contributor.author | Ng, Victor Wee Lin | |
| dc.contributor.author | Schrock, Richard Royce | |
| dc.date.accessioned | 2012-03-08T16:22:37Z | |
| dc.date.available | 2012-03-08T16:22:37Z | |
| dc.date.issued | 2011-01 | |
| dc.date.submitted | 2010-12 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/69594 | |
| dc.description.abstract | Ring-opening metathesis polymerization (ROMP) of rac-endo,exo-5,6-dicarbomethoxynorbornene (inter alia) yields a cis,syndio,alt-polymer, one in which the sequential units in the cis,syndiotactic polymer consist of alternating enantiomers. Cis selectivity arises through addition of the monomer to produce an all-cis-metallacyclobutane intermediate, while syndioselectivity and alternating enantiomer structures arise as a consequence of inversion of configuration at the metal center with each metathesis step. | en_US |
| dc.description.sponsorship | United States. Army Research Office (Institute for Soldier Nanotechnologies, Contract No. DAAD-19-02-D-0002) | en_US |
| dc.description.sponsorship | United States. Dept. of Energy (DE-FG02- 86-ER13564) | en_US |
| dc.description.sponsorship | Singapore. Agency for Science, Technology and Research (A*STAR International Fellowship) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja110949f | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | Prof. Schrock via Erja Kajosalo | en_US |
| dc.title | Synthesis of Cis,Syndiotactic ROMP Polymers Containing Alternating Enantiomers | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Flook, Margaret M., Victor W. L. Ng, and Richard R. Schrock. “Synthesis of Cis,syndiotactic ROMP Polymers Containing Alternating Enantiomers.” Journal of the American Chemical Society 133.6 (2011): 1784–1786. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Schrock, Richard Royce | |
| dc.contributor.mitauthor | Flook, Margaret M. | |
| dc.contributor.mitauthor | Ng, Victor Wee Lin | |
| dc.contributor.mitauthor | Schrock, Richard Royce | |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Flook, Margaret M.; Ng, Victor W. L.; Schrock, Richard R. | en |
| dc.identifier.orcid | https://orcid.org/0000-0001-5827-3552 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
