Endo-Selective Enyne Ring- Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes

Author(s)
Zhao, Yu; Hoveyda, Amir H.; Schrock, Richard Royce
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Abstract
The utility of W-alkylidene complexes for enyne ring-closing metathesis is demonstrated in a direct comparison with Mo-based analogs. Tungsten complexes lead to less alkyne oligomerization and higher levels of endo-selectivity and enantioselectivity.
Date issued
2011-01
URI
http://hdl.handle.net/1721.1/69936
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Organic Letters
Publisher
American Chemical Society
Citation
Zhao, Yu, Amir H. Hoveyda, and Richard R. Schrock. “Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes.” Organic Letters 13.4 (2011): 784–787.
Version: Author's final manuscript
ISSN
1523-7060
1523-7052
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