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Identification of Protein-Bound Dinitrosyl Iron Complexes by Nuclear Resonance Vibrational Spectroscopy

dc.contributor.authorWang, Hongxin
dc.contributor.authorMitra, Devrani
dc.contributor.authorTinberg, Christine E.
dc.contributor.authorDo, Loi Hung
dc.contributor.authorJenney, Francis E., Jr.
dc.contributor.authorAdams, Michael W. W.
dc.contributor.authorCramer, Stephen P.
dc.contributor.authorLippard, Stephen J.
dc.date.accessioned2012-08-01T15:56:48Z
dc.date.available2012-08-01T15:56:48Z
dc.date.issued2010-04
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.urihttp://hdl.handle.net/1721.1/71931
dc.description.abstractWe have applied [superscript 57]Fe nuclear resonance vibrational spectroscopy (NRVS) to identify protein-bound dinitrosyl iron complexes. Intense NRVS peaks due to vibrations of the N−Fe−N unit can be observed between 500 and 700 cm[superscript −1] and are diagnostic indicators of the type of iron dinitrosyl species present. NRVS spectra for four iron dinitrosyl model compounds are presented and used as benchmarks for the identification of species formed in the reaction of Pyrococcus furiosus ferredoxin D14C with nitric oxide.en_US
dc.description.sponsorshipNational Science Foundation (Grant Number CHE-0611944)en_US
dc.description.sponsorshipNational Institute of General Medical Sciences (U.S.). Interdepartmental Training (Grant Number T32 GM08334)en_US
dc.description.sponsorshipNational Institute of General Medical Sciences (U.S.). Postdoctural Fellowship (1 F32 GM082031-02)en_US
dc.language.isoen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/ja101002fen_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourcePMCen_US
dc.titleIdentification of Protein-Bound Dinitrosyl Iron Complexes by Nuclear Resonance Vibrational Spectroscopyen_US
dc.typeArticleen_US
dc.identifier.citationTonzetich, Zachary J. et al. “Identification of Protein-Bound Dinitrosyl Iron Complexes by Nuclear Resonance Vibrational Spectroscopy.” Journal of the American Chemical Society 132.20 (2010): 6914–6916.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.approverLippard, Stephen J.
dc.contributor.mitauthorTonzetich, Zachary J.
dc.contributor.mitauthorTinberg, Christine E.
dc.contributor.mitauthorDo, Loi Hung
dc.contributor.mitauthorLippard, Stephen J.
dc.relation.journalJournal of the American Chemical Societyen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsTonzetich, Zachary J.; Wang, Hongxin; Mitra, Devrani; Tinberg, Christine E.; Do, Loi H.; Jenney, Francis E.; Adams, Michael W. W.; Cramer, Stephen P.; Lippard, Stephen J.en
dc.identifier.orcidhttps://orcid.org/0000-0002-2693-4982
dspace.mitauthor.errortrue
mit.licensePUBLISHER_POLICYen_US
mit.metadata.statusComplete


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