Observations in the Synthesis of the Core of the Antitumor Illudins via an Enyne Ring Closing Metathesis Cascade
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Observations concerning the synthesis of the core spirocyclic AB-ring system of illudins using an enyne ring closing metathesis (EYRCM) cascade are discussed. Substituent effects, in addition to optimization of the reaction conditions and the olefin tether for the key EYRCM reaction, are examined.
Date issued
2009-07Department
Massachusetts Institute of Technology. Department of ChemistryJournal
Tetrahedron Letters
Publisher
Elsevier
Citation
Movassaghi, Mohammad et al. “Observations in the Synthesis of the Core of the Antitumor Illudins via an Enyne Ring Closing Metathesis Cascade.” Tetrahedron Letters 50.39 (2009): 5489–5492.
Version: Author's final manuscript
ISSN
0040-4039
0040-4039