Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides

Author(s)
Shen, Xiaoqiang; Hyde, Alan M.; Buchwald, Stephen Leffler
Thumbnail
DownloadBuchwald_Palladium-Catalyzed.pdf (679.0Kb)
PUBLISHER_POLICY
Terms of use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Metadata
Show full item record
Abstract
The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in good to excellent yields.
Date issued
2010
URI
http://hdl.handle.net/1721.1/72343
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Shen, Xiaoqiang, Alan M. Hyde, and Stephen L. Buchwald. “Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides.” Journal of the American Chemical Society 132.40 (2010): 14076–14078.
Version: Author's final manuscript
ISSN
0002-7863
1520-5126
Collections