Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
Author(s)Shen, Xiaoqiang; Hyde, Alan M.; Buchwald, Stephen Leffler
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The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in good to excellent yields.
DepartmentMassachusetts Institute of Technology. Department of Chemistry
Journal of the American Chemical Society
American Chemical Society (ACS)
Shen, Xiaoqiang, Alan M. Hyde, and Stephen L. Buchwald. “Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides.” Journal of the American Chemical Society 132.40 (2010): 14076–14078.
Author's final manuscript