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Claisen Rearrangement of Graphite Oxide: A Route to Covalently Functionalized Graphenes

dc.contributor.authorCollins, William R.
dc.contributor.authorLewandowski, Wiktor
dc.contributor.authorSchmois, Ezequiel
dc.contributor.authorWalish, Joseph John
dc.contributor.authorSwager, Timothy M
dc.date.accessioned2012-10-24T16:30:11Z
dc.date.available2012-10-24T16:30:11Z
dc.date.issued2011-08
dc.date.submitted2011-07
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttp://hdl.handle.net/1721.1/74222
dc.description.abstractOn the GO: The basal plane allylic alcohol functionality of graphite oxide (GO) can be converted into N,N-dimethylamide groups through an Eschenmoser–Claisen sigmatropic rearrangement by using N,N-dimethylacetamide dimethyl acetal. Subsequent saponification of these groups affords the carboxylic acids (see picture), which, when deprotonated, electrostatically stabilize the graphene sheets in an aqueous environment.en_US
dc.description.sponsorshipMassachusetts Institute of Technology. Institute for Soldier Nanotechnologiesen_US
dc.description.sponsorshipUnited States. Intelligence Community (IC) Postdoctoral Research Fellowship Programen_US
dc.language.isoen_US
dc.publisherWiley Blackwellen_US
dc.relation.isversionofhttp://dx.doi.org/10.1002/anie.201101371en_US
dc.rightsCreative Commons Attribution-Noncommercial-Share Alike 3.0en_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/en_US
dc.sourceProf. Swager via Erja Kajosaloen_US
dc.titleClaisen Rearrangement of Graphite Oxide: A Route to Covalently Functionalized Graphenesen_US
dc.typeArticleen_US
dc.identifier.citationCollins, William R. et al. “Claisen Rearrangement of Graphite Oxide: A Route to Covalently Functionalized Graphenes.” Angewandte Chemie International Edition 50.38 (2011): 8848–8852.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Institute for Soldier Nanotechnologiesen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemical Engineeringen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.approverSwager, Timothy M.
dc.contributor.mitauthorCollins, William R.
dc.contributor.mitauthorLewandowski, Wiktor
dc.contributor.mitauthorSchmois, Ezequiel
dc.contributor.mitauthorWalish, Joseph
dc.contributor.mitauthorSwager, Timothy Manning
dc.relation.journalAngewandte Chemie International Editionen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsCollins, William R.; Lewandowski, Wiktor; Schmois, Ezequiel; Walish, Joseph; Swager, Timothy M.en
dc.identifier.orcidhttps://orcid.org/0000-0002-3503-2120
mit.licenseOPEN_ACCESS_POLICYen_US
mit.metadata.statusComplete


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