Synthesis of a BDPA-TEMPO Biradical

Author(s)
Dane, Eric L.; Maly, Thorsten; Debelouchina, Galia Tzvetanova; Griffin, Robert Guy; Swager, Timothy M
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Abstract
The synthesis and characterization of a biradical containing a 1,3-bisdiphenylene-2-phenylallyl (BDPA) free radical covalently attached to a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) free radical are described. The synthesis of the biradical is a step toward improved polarizing agents for dynamic nuclear polarization (DNP).
Date issued
2009-03
URI
http://hdl.handle.net/1721.1/74224
Department
Massachusetts Institute of Technology. Department of Chemistry; Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology)
Journal
Organic Letters
Publisher
American Chemical Society
Citation
Dane, Eric L. et al. “Synthesis of a BDPA-TEMPO Biradical.” Organic Letters 11.9 (2009): 1871–1874. Web.
Version: Author's final manuscript
ISSN
1523-7060
1523-7052
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