| dc.contributor.author | Swager, Timothy Manning | |
| dc.contributor.author | Vanveller, Brett Steven | |
| dc.contributor.author | Robinson, Dale | |
| dc.date.accessioned | 2012-10-24T17:01:55Z | |
| dc.date.available | 2012-10-24T17:01:55Z | |
| dc.date.issued | 2011-12 | |
| dc.date.submitted | 2011-10 | |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.issn | 1521-3773 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/74226 | |
| dc.description.abstract | At level best: A strategic synthesis of a new class of poly(p-phenylene vinylene)-bearing annulated alkene units from a parent poly(p-phenylene ethynylene) is described (see scheme). The gold-mediated cycloisomerization reaction of alkynes with appended hydroxy-group reacting partners delivers products having a stark increase in chain rigidity and planarity, as evidenced by pronounced photophysical changes. | en_US |
| dc.description.sponsorship | Natural Sciences and Engineering Research Council of Canada (NSERC) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.). Bioengineering Research Partnership (Grant R01 AG026240-01A1) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Wiley Blackwell | en_US |
| dc.relation.isversionof | http://dx.doi.org/ 10.1002/anie.201106985 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
| dc.source | Prof. Swager via Erja Kajosalo | en_US |
| dc.title | Triptycene Diols: A Strategy for Synthesizing Planar pi Systems through Catalytic Conversion of a Poly(p-phenylene ethynylene) into a Poly(p-phenylene vinylene) | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | VanVeller, Brett, Dale Robinson, and Timothy M. Swager. “Triptycene Diols: A Strategy for Synthesizing Planar π Systems Through Catalytic Conversion of a Poly(p-phenylene Ethynylene) into a Poly(p-phenylene Vinylene).” Angewandte Chemie International Edition 51.5 (2012): 1182–1186. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Swager, Timothy Manning | |
| dc.contributor.mitauthor | Swager, Timothy Manning | |
| dc.contributor.mitauthor | Vanveller, Brett Steven | |
| dc.contributor.mitauthor | Robinson, Dale | |
| dc.relation.journal | Angewandte Chemie International Edition | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | VanVeller, Brett; Robinson, Dale; Swager, Timothy M. | en |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
