Synthesis of a Water-Soluble 1,3-Bis(diphenylene)2-phenylallyl Radical

Author(s)
Swager, Timothy Manning; Dane, Eric L.
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Abstract
The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear polarization NMR. Its 9 GHz EPR spectrum in glycerol/water is reported.
Date issued
2010-04
URI
http://hdl.handle.net/1721.1/74228
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of Organic Chemistry
Publisher
American Chemical Society (ACS)
Citation
Dane, Eric L., and Timothy M. Swager. “Synthesis of a Water-Soluble 1,3-Bis(diphenylene)-2-phenylallyl Radical.” The Journal of Organic Chemistry 75.10 (2010): 3533–3536.
Version: Author's final manuscript
ISSN
0022-3263
1520-6904
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