Synthesis of a Water-Soluble 1,3-Bis(diphenylene)2-phenylallyl Radical
Author(s)Swager, Timothy Manning; Dane, Eric L.
MetadataShow full item record
The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear polarization NMR. Its 9 GHz EPR spectrum in glycerol/water is reported.
DepartmentMassachusetts Institute of Technology. Department of Chemistry
Journal of Organic Chemistry
American Chemical Society (ACS)
Dane, Eric L., and Timothy M. Swager. “Synthesis of a Water-Soluble 1,3-Bis(diphenylene)-2-phenylallyl Radical.” The Journal of Organic Chemistry 75.10 (2010): 3533–3536.
Author's final manuscript