Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits
Author(s)Swager, Timothy Manning; Chan, Julian M. W.; Kooi, Steven Earl
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Polycyclic aromatic monomers based on substituted dibenz[a,h]anthracene frameworks have been prepared in high yields. From these, several fluorescent stair-stepped conjugated polymers containing fused aromatic subunits have been synthesized via Sonogashira polycondensations and Glaser-type oxidative couplings. The new polymers were characterized by NMR spectroscopy, gel-permeation chromatography (GPC), UV−vis, and fluorescence spectroscopy.
DepartmentMassachusetts Institute of Technology. Institute for Soldier Nanotechnologies; Massachusetts Institute of Technology. Department of Chemistry
American Chemical Society (ACS)
Chan, Julian M. W., Steven E. Kooi, and Timothy M. Swager. “Synthesis of Stair-Stepped Polymers Containing Dibenz[a,h]anthracene Subunits.” Macromolecules 43.6 (2010): 2789–2793.
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