| dc.contributor.author | Matsubara, Ryosuke | |
| dc.contributor.author | Gutierrez, Alicia C. | |
| dc.contributor.author | Jamison, Timothy F. | |
| dc.date.accessioned | 2013-01-08T16:10:07Z | |
| dc.date.available | 2013-01-08T16:10:07Z | |
| dc.date.issued | 2011-11 | |
| dc.date.submitted | 2011-03 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/76192 | |
| dc.description.abstract | Nickel-catalyzed intermolecular benzylation and heterobenzylation of unactivated alkenes to provide functionalized allylbenzene derivatives are described. A wide range of both the benzyl chloride and alkene coupling partners are tolerated. In contrast to analogous palladium-catalyzed variants of this process, all reactions described herein employ electronically unbiased aliphatic olefins (including ethylene), proceed at room temperature, and provide 1,1-disubstituted olefins over the more commonly observed 1,2-disubstituted olefins with very high selectivity. | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/ 10.1021/ja209235d | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | Prof. Jamison via Erja Kajosalo | en_US |
| dc.title | Nickel-Catalyzed Heck-Type Reactions of Benzyl Chlorides and Simple Olefins | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Matsubara, Ryosuke, Alicia C. Gutierrez, and Timothy F. Jamison. “Nickel-Catalyzed Heck-Type Reactions of Benzyl Chlorides and Simple Olefins.” Journal of the American Chemical Society 133.47 (2011): 19020–19023. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Jamison, Timothy F. | |
| dc.contributor.mitauthor | Matsubara, Ryosuke | |
| dc.contributor.mitauthor | Gutierrez, Alicia C. | |
| dc.contributor.mitauthor | Jamison, Timothy F. | |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Matsubara, Ryosuke; Gutierrez, Alicia C.; Jamison, Timothy F. | en |
| dc.identifier.orcid | https://orcid.org/0000-0002-8601-7799 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
