First Principles Study of the Li[subscript 10]GeP[subscript 2]S[subscript 12] Lithium Super Ionic Conductor Material
Author(s)
Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
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The continued drive for high performance lithium batteries has imposed stricter requirements on the electrolyte materials. Solid electrolytes comprising lithium super ionic conductor materials exhibit good safety and stability and are promising to replace current organic liquid electrolytes. One major limitation in the application of Li-ion conductors is that their typical conductivity is less than 10[superscript −4] S/cm at room temperature. Recently, Kamaya et al. reported a new Li super ionic conductor Li[subscript 10]GeP[subscript 2]S[subscript 12] (LGPS), which has the highest conductivity ever achieved among solid lithium electrolytes of 12 mS/cm at room temperature (comparable conductivity with liquid electrolytes) and outstanding electrochemical performance in Li batteries.
Date issued
2011-12Department
Massachusetts Institute of Technology. Department of Materials Science and EngineeringJournal
Chemistry of Materials
Publisher
American Chemical Society (ACS)
Citation
Mo, Yifei, Shyue Ping Ong, and Gerbrand Ceder. “First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material.” Chemistry of Materials 24, no. 1 (January 10, 2012): 15-17.
Version: Author's final manuscript
ISSN
0897-4756
1520-5002