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Palladium(0)-Catalyzed Intermolecular Amination of Unactivated C[3 over sp]-H Bonds

Author(s)
Pan, Jun; Su, Mingjuan; Buchwald, Stephen Leffler
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Abstract
Filling out the space: The title reaction of unactivated C[3 over sp]-H bonds using aryl amines as the nitrogen source is disclosed (see scheme; dba=dibenzylideneacetone, Tf=trifluoromethanesulfonyl). Either the C-N cross-coupling product or the C-H amination product could be accessed selectively by adjusting the steric environment of the substrate.
Date issued
2011-08
URI
http://hdl.handle.net/1721.1/81942
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Angewandte Chemie International Edition
Publisher
Wiley Blackwell
Citation
Pan, Jun, Mingjuan Su, and Stephen L. Buchwald. “Palladium(0)-Catalyzed Intermolecular Amination of Unactivated C[3 over sp]-H Bonds.” Angewandte Chemie International Edition 50, no. 37 (September 5, 2011): 8647-8651.
Version: Author's final manuscript
ISSN
14337851
1521-3773

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