Narrow-Band Absorption-Enhanced Quantum Dot/J-Aggregate Conjugates

Abstract

We report narrow-band absorption enhancement of semiconductor nanocrystals via Förster resonance energy transfer from cyanine J-aggregates. These J-aggregated dyes associate electrostatically with short quantum-dot (QD) surface ligands in solution. Energy transfer efficiencies approach unity for this light sensitization and result in a 5-fold enhancement in the QD excitation near the J-aggregate absorption maximum. Because a thin layer of J-aggregates attenuates the same amount of light (at peak absorbance) as a far thicker film of monomer dye, these absorption-enhanced materials may have applications in light-sensitizing applications such as photodetection and optical down-conversion.