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dc.contributor.authorCaporini, Marc A.
dc.contributor.authorTurner, Christopher John
dc.contributor.authorBielecki, Anthony
dc.contributor.authorGriffin, Robert Guy
dc.date.accessioned2013-11-08T19:38:24Z
dc.date.available2013-11-08T19:38:24Z
dc.date.issued2009-10
dc.identifier.issn10907807
dc.identifier.urihttp://hdl.handle.net/1721.1/82061
dc.description.abstractMagic angle spinning (MAS) is used in solid-state NMR to remove the broadening effects of the chemical shift anisotropy (CSA). In this work we investigate a technique that can reintroduce the CSA in order to selectively invert transverse magnetization. The technique involves an amplitude sweep of the radio frequency field through a multiple of the spinning frequency. The selectivity of this inversion mechanism is determined by the size of the CSA. We develop a theoretical framework to describe this process and demonstrate the CSA selective inversion with numerical simulations and experimental data. We combine this approach with cross-polarization (CP) for potential applications in multi-dimensional MAS NMR.en_US
dc.description.sponsorshipNational Institute of Biomedical Imaging and Bioengineering (U.S.) (Grant EB-003151)en_US
dc.language.isoen_US
dc.publisherElsevier B.V.en_US
dc.relation.isversionofhttp://dx.doi.org/10.1016/j.jmr.2009.07.003en_US
dc.rightsCreative Commons Attribution-Noncommercial-Share Alike 3.0en_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/en_US
dc.sourcePMCen_US
dc.titleChemical shift anisotropy selective inversionen_US
dc.typeArticleen_US
dc.identifier.citationCaporini, Marc A., Christopher J. Turner, Anthony Bielecki, and Robert G. Griffin. “Chemical shift anisotropy selective inversion.” Journal of Magnetic Resonance 200, no. 2 (October 2009): 233-238.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.mitauthorCaporini, Marc A.en_US
dc.contributor.mitauthorGriffin, Robert Guyen_US
dc.contributor.mitauthorTurner, Christopher Johnen_US
dc.contributor.mitauthorBielecki, Anthonyen_US
dc.relation.journalJournal of Magnetic Resonanceen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsCaporini, Marc A.; Turner, Christopher J.; Bielecki, Anthony; Griffin, Robert G.en_US
dc.identifier.orcidhttps://orcid.org/0000-0003-1589-832X
mit.licenseOPEN_ACCESS_POLICYen_US


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