| dc.contributor.author | Kiesewetter, Matthew K. | |
| dc.contributor.author | Smith, Albert A. | |
| dc.contributor.author | Corzilius, Bjorn | |
| dc.contributor.author | Griffin, Robert Guy | |
| dc.contributor.author | Swager, Timothy M | |
| dc.date.accessioned | 2013-11-12T13:26:05Z | |
| dc.date.available | 2013-11-12T13:26:05Z | |
| dc.date.issued | 2012-02 | |
| dc.date.submitted | 2011-12 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/82074 | |
| dc.description.abstract | A new biradical polarizing agent, bTbtk-py, for dynamic nuclear polarization (DNP) experiments in aqueous media is reported. The synthesis is discussed in light of the requirements of the optimum, theoretical, biradical system. To date, the DNP NMR signal enhancement resulting from bTbtk-py is the largest of any biradical in the ideal glycerol/water solvent matrix, ε = 230. EPR and X-ray crystallography are used to characterize the molecule and suggest approaches for further optimizing the biradical distance and relative orientation. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM095843) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (EB002804) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (EB002026) | en_US |
| dc.description.sponsorship | National Institute for Biomedical Imaging and Bioengineering (U.S.) (NRSA Fellowship F32EB012937) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja212054e | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Dynamic Nuclear Polarization with a Water-Soluble Rigid Biradical | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Kiesewetter, Matthew K., Bjorn Corzilius, Albert A. Smith, Robert G. Griffin, and Timothy M. Swager. “Dynamic Nuclear Polarization with a Water-Soluble Rigid Biradical.” Journal of the American Chemical Society 134, no. 10 (March 14, 2012): 4537-4540. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.department | Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) | en_US |
| dc.contributor.mitauthor | Kiesewetter, Matthew K. | en_US |
| dc.contributor.mitauthor | Corzilius, Bjorn | en_US |
| dc.contributor.mitauthor | Smith, Albert A. | en_US |
| dc.contributor.mitauthor | Griffin, Robert Guy | en_US |
| dc.contributor.mitauthor | Swager, Timothy Manning | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Kiesewetter, Matthew K.; Corzilius, Bjorn; Smith, Albert A.; Griffin, Robert G.; Swager, Timothy M. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-1589-832X | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
