dc.contributor.author | Michaelis, Vladimir K. | |
dc.contributor.author | Markhasin, Evgeny | |
dc.contributor.author | Daviso, Eugenio | |
dc.contributor.author | Herzfeld, Judith | |
dc.contributor.author | Griffin, Robert Guy | |
dc.date.accessioned | 2013-11-12T14:04:10Z | |
dc.date.available | 2013-11-12T14:04:10Z | |
dc.date.issued | 2012-07 | |
dc.date.submitted | 2012-06 | |
dc.identifier.issn | 1948-7185 | |
dc.identifier.uri | http://hdl.handle.net/1721.1/82078 | |
dc.description.abstract | Oxygen-17-detected DNP NMR of a water/glycerol glass enabled an 80-fold enhancement of signal intensity at 82 K, using the biradical TOTAPOL. The >6000-fold savings in acquisition time enable [superscript 17]O–[superscript 1]H distance measurements and heteronuclear correlation experiments. These experiments are the initial demonstration of the feasibility of DNP NMR on quadrupolar [superscript 17]O. | en_US |
dc.description.sponsorship | National Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-001960) | en_US |
dc.description.sponsorship | National Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-002804) | en_US |
dc.description.sponsorship | National Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-001035) | en_US |
dc.description.sponsorship | National Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-002026) | en_US |
dc.language.iso | en_US | |
dc.publisher | American Chemical Society (ACS) | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1021/jz300742w | en_US |
dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
dc.source | PMC | en_US |
dc.title | Dynamic Nuclear Polarization of Oxygen-17 | en_US |
dc.type | Article | en_US |
dc.identifier.citation | Michaelis, Vladimir K., Evgeny Markhasin, Eugenio Daviso, Judith Herzfeld, and Robert G. Griffin. “Dynamic Nuclear Polarization of Oxygen-17.” The Journal of Physical Chemistry Letters 3, no. 15 (August 2, 2012): 2030-2034. | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
dc.contributor.department | Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) | en_US |
dc.contributor.mitauthor | Michaelis, Vladimir K. | en_US |
dc.contributor.mitauthor | Markhasin, Evgeny | en_US |
dc.contributor.mitauthor | Daviso, Eugenio | en_US |
dc.contributor.mitauthor | Griffin, Robert Guy | en_US |
dc.relation.journal | The Journal of Physical Chemistry Letters | en_US |
dc.eprint.version | Author's final manuscript | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dspace.orderedauthors | Michaelis, Vladimir K.; Markhasin, Evgeny; Daviso, Eugenio; Herzfeld, Judith; Griffin, Robert G. | en_US |
dc.identifier.orcid | https://orcid.org/0000-0003-1589-832X | |
dc.identifier.orcid | https://orcid.org/0000-0002-6708-7660 | |
mit.license | PUBLISHER_POLICY | en_US |
mit.metadata.status | Complete | |