The MIT Libraries is completing a major upgrade to DSpace@MIT. Starting May 5 2026, DSpace will remain functional, viewable, searchable, and downloadable, however, you will not be able to edit existing collections or add new material. We are aiming to have full functionality restored by May 18, 2026, but intermittent service interruptions may occur. Please email dspace-lib@mit.edu with any questions. Thank you for your patience as we implement this important upgrade.

Show simple item record

dc.contributor.authorMichaelis, Vladimir K.
dc.contributor.authorMarkhasin, Evgeny
dc.contributor.authorDaviso, Eugenio
dc.contributor.authorHerzfeld, Judith
dc.contributor.authorGriffin, Robert Guy
dc.date.accessioned2013-11-12T14:04:10Z
dc.date.available2013-11-12T14:04:10Z
dc.date.issued2012-07
dc.date.submitted2012-06
dc.identifier.issn1948-7185
dc.identifier.urihttp://hdl.handle.net/1721.1/82078
dc.description.abstractOxygen-17-detected DNP NMR of a water/glycerol glass enabled an 80-fold enhancement of signal intensity at 82 K, using the biradical TOTAPOL. The >6000-fold savings in acquisition time enable [superscript 17]O–[superscript 1]H distance measurements and heteronuclear correlation experiments. These experiments are the initial demonstration of the feasibility of DNP NMR on quadrupolar [superscript 17]O.en_US
dc.description.sponsorshipNational Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-001960)en_US
dc.description.sponsorshipNational Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-002804)en_US
dc.description.sponsorshipNational Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-001035)en_US
dc.description.sponsorshipNational Institute for Biomedical Imaging and Bioengineering (U.S.) (Award EB-002026)en_US
dc.language.isoen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/jz300742wen_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourcePMCen_US
dc.titleDynamic Nuclear Polarization of Oxygen-17en_US
dc.typeArticleen_US
dc.identifier.citationMichaelis, Vladimir K., Evgeny Markhasin, Eugenio Daviso, Judith Herzfeld, and Robert G. Griffin. “Dynamic Nuclear Polarization of Oxygen-17.” The Journal of Physical Chemistry Letters 3, no. 15 (August 2, 2012): 2030-2034.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.departmentFrancis Bitter Magnet Laboratory (Massachusetts Institute of Technology)en_US
dc.contributor.mitauthorMichaelis, Vladimir K.en_US
dc.contributor.mitauthorMarkhasin, Evgenyen_US
dc.contributor.mitauthorDaviso, Eugenioen_US
dc.contributor.mitauthorGriffin, Robert Guyen_US
dc.relation.journalThe Journal of Physical Chemistry Lettersen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsMichaelis, Vladimir K.; Markhasin, Evgeny; Daviso, Eugenio; Herzfeld, Judith; Griffin, Robert G.en_US
dc.identifier.orcidhttps://orcid.org/0000-0003-1589-832X
dc.identifier.orcidhttps://orcid.org/0000-0002-6708-7660
mit.licensePUBLISHER_POLICYen_US
mit.metadata.statusComplete


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record