| dc.contributor.author | Owston, Nathan A. | |
| dc.contributor.author | Fu, Gregory C. | |
| dc.date.accessioned | 2013-11-15T14:21:40Z | |
| dc.date.available | 2013-11-15T14:21:40Z | |
| dc.date.issued | 2010-09 | |
| dc.date.submitted | 2010-07 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/82112 | |
| dc.description.abstract | A method for asymmetric alkyl−alkyl Suzuki reactions of unactivated secondary alkyl electrophiles, specifically, cross-couplings of racemic acylated halohydrins with alkylborane reagents, has been developed. A range of protected bromohydrins, as well as a protected chlorohydrin and a homologated bromohydrin, are coupled in good ee by a catalyst derived from commercially available components. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (National Institute of General Medical Sciences, Grant R01- GM62871) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja105924f | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Asymmetric Alkyl−Alkyl Cross-Couplings of Unactivated Secondary Alkyl Electrophiles: Stereoconvergent Suzuki Reactions of Racemic Acylated Halohydrins | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Owston, Nathan A., and Gregory C. Fu. “Asymmetric Alkyl−Alkyl Cross-Couplings of Unactivated Secondary Alkyl Electrophiles: Stereoconvergent Suzuki Reactions of Racemic Acylated Halohydrins.” Journal of the American Chemical Society 132, no. 34 (September 2010): 11908-11909. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Owston, Nathan A. | en_US |
| dc.contributor.mitauthor | Fu, Gregory C. | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Owston, Nathan A.; Fu, Gregory C. | en_US |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
