| dc.contributor.author | Tanuwidjaja, Jessica | |
| dc.contributor.author | Ng, Sze-Sze | |
| dc.contributor.author | Jamison, Timothy F. | |
| dc.date.accessioned | 2013-11-15T15:02:17Z | |
| dc.date.available | 2013-11-15T15:02:17Z | |
| dc.date.issued | 2009-08 | |
| dc.date.submitted | 2009-06 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/82115 | |
| dc.description.abstract | In the first total synthesis of ent-dioxepandehydrothyrsiferol, the signature trans-anti-trans 7,7,6-fused tricyclic polyether framework was constructed in a single bromonium-initiated epoxide-opening cascade that incorporates both endo- and exo-selective epoxide openings, each directed by the substitution pattern of the epoxide (methyl groups). This study thus demonstrates the feasibility of a possible biogenesis. | en_US |
| dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (GM-72566) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja9052366 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Total Synthesis of ent-Dioxepandehydrothyrsiferol via a Bromonium-Initiated Epoxide-Opening Cascade | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Tanuwidjaja, Jessica, Sze-Sze Ng, and Timothy F. Jamison. “Total Synthesis of ent-Dioxepandehydrothyrsiferol via a Bromonium-Initiated Epoxide-Opening Cascade.” Journal of the American Chemical Society 131, no. 34 (September 2, 2009): 12084-12085. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Tanuwidjaja, Jessica | en_US |
| dc.contributor.mitauthor | Ng, Sze-Sze | en_US |
| dc.contributor.mitauthor | Jamison, Timothy F. | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Tanuwidjaja, Jessica; Ng, Sze-Sze; Jamison, Timothy F. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0002-8601-7799 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
