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dc.contributor.authorLi, Yang
dc.contributor.authorWilson, Justin J.
dc.contributor.authorDo, Loi Hung
dc.contributor.authorApfel, Ulf-Peter
dc.contributor.authorLippard, Stephen J.
dc.date.accessioned2013-11-18T19:39:13Z
dc.date.available2013-11-18T19:39:13Z
dc.date.issued2012-06
dc.date.submitted2012-05
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.urihttp://hdl.handle.net/1721.1/82459
dc.description.abstractA triptycene-based bis(benzoxazole) diacid ligand H[subscript 2]L2[superscript Ph4] bearing sterically encumbering groups was synthesized. Treatment of H[subscript 2]L2[superscript Ph4] with Fe(OTf)[subscript 3] afforded a C[subscript 2]-symmetric trinuclear iron(III) complex, [NaFe[subscript 3](L2[superscript Ph4])[subscript 2](μ[subscript 3]-O)(μ-O[subscript 2]CCPh[subscript 3])[subscript 2](H[subscript 2]O)[subscript 3]](OTf)[subscript 2] (8). The triiron core of this complex adopts the well known “basic iron acetate” structure where the heteroleptic carboxylates, comprising two Ph[subscript 3]CCO[− over 2] and two (L2[superscript Ph4])[superscript 2−] ligands, donate the six carboxylate bridges. The (L2[superscript Ph4])[superscript 2−] ligand undergoes only minor conformational changes upon formation of the complex.en_US
dc.description.sponsorshipNational Institute of General Medical Sciences (U.S.) (GM-032134)en_US
dc.language.isoen_US
dc.publisherRoyal Society of Chemistry, Theen_US
dc.relation.isversionofhttp://dx.doi.org/10.1039/c2dt31260cen_US
dc.rightsCreative Commons Attribution-Noncommercial-Share Alike 3.0en_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/en_US
dc.sourcePMCen_US
dc.titleA C[subscript 2]-symmetric, basic Fe(iii) carboxylate complex derived from a novel triptycene-based chelating carboxylate liganden_US
dc.typeArticleen_US
dc.identifier.citationLi, Yang, Justin J. Wilson, Loi H. Do, Ulf-Peter Apfel, and Stephen J. Lippard. “A C2-symmetric, basic Fe(iii) carboxylate complex derived from a novel triptycene-based chelating carboxylate ligand.” Dalton Transactions 41, no. 31 (2012): 9272.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.mitauthorLi, Yangen_US
dc.contributor.mitauthorWilson, Justin J.en_US
dc.contributor.mitauthorDo, Loi Hungen_US
dc.contributor.mitauthorApfel, Ulf-Peteren_US
dc.contributor.mitauthorLippard, Stephen J.en_US
dc.relation.journalDalton Transactionsen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsLi, Yang; Wilson, Justin J.; Do, Loi H.; Apfel, Ulf-Peter; Lippard, Stephen J.en_US
dc.identifier.orcidhttps://orcid.org/0000-0002-1577-2420
dc.identifier.orcidhttps://orcid.org/0000-0002-2693-4982
dspace.mitauthor.errortrue
mit.licenseOPEN_ACCESS_POLICYen_US


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