Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines
Author(s)Han, Sunkyu; Movassaghi, Mohammad
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The concise and enantioselective total syntheses of (−)-trigonoliimines A, B, and C are described. Our unified strategy to all three natural products is based on asymmetric oxidation and reorganization of a single bistryptamine, a sequence of transformations with possible biogenetic relevance. We revise the absolute stereochemistry of (−)-trigonoliimines A, B, and C.
DepartmentMassachusetts Institute of Technology. Department of Chemistry
Journal of the American Chemical Society
American Chemical Society (ACS)
Han, Sunkyu, and Mohammad Movassaghi. “Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines.” Journal of the American Chemical Society 133, no. 28 (July 20, 2011): 10768-10771.
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