Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines

Author(s)
Han, Sunkyu; Movassaghi, Mohammad
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Abstract
The concise and enantioselective total syntheses of (−)-trigonoliimines A, B, and C are described. Our unified strategy to all three natural products is based on asymmetric oxidation and reorganization of a single bistryptamine, a sequence of transformations with possible biogenetic relevance. We revise the absolute stereochemistry of (−)-trigonoliimines A, B, and C.
Date issued
2011-06
URI
http://hdl.handle.net/1721.1/82467
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Han, Sunkyu, and Mohammad Movassaghi. “Concise Total Synthesis and Stereochemical Revision of all (−)-Trigonoliimines.” Journal of the American Chemical Society 133, no. 28 (July 20, 2011): 10768-10771.
Version: Author's final manuscript
ISSN
0002-7863
1520-5126
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