| dc.contributor.author | Hoveyda, Amir H. | |
| dc.contributor.author | Townsend, Erik Matthew | |
| dc.contributor.author | Schrock, Richard Royce | |
| dc.date.accessioned | 2013-11-22T20:17:27Z | |
| dc.date.available | 2013-11-22T20:17:27Z | |
| dc.date.issued | 2012-06 | |
| dc.date.submitted | 2012-04 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/82561 | |
| dc.description.abstract | Molybdenum or tungsten monoaryloxide pyrrolide (MAP) complexes that contain OHIPT as the aryloxide (hexaisopropylterphenoxide) are effective catalysts for homocoupling of simple (E)-1,3-dienes to give (E,Z,E)-trienes in high yield and with high Z selectivities. A vinylalkylidene MAP species was shown to have the expected syn structure in an X-ray study. MAP catalysts that contain OHMT (hexamethylterphenoxide) are relatively inefficient. | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (CHE-0841187) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (CHE-1111133) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant GM-59426) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (CHE-0946721) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja303220j | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Townsend, Erik M., Richard R. Schrock, and Amir H. Hoveyda. “Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes.” Journal of the American Chemical Society 134, no. 28 (July 18, 2012): 11334-11337. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Townsend, Erik Matthew | en_US |
| dc.contributor.mitauthor | Schrock, Richard Royce | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Townsend, Erik M.; Schrock, Richard R.; Hoveyda, Amir H. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0001-5827-3552 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
