| dc.contributor.author | Marinescu, Smaranda C. | |
| dc.contributor.author | Levine, Daniel S. | |
| dc.contributor.author | Zhao, Yu | |
| dc.contributor.author | Schrock, Richard Royce | |
| dc.contributor.author | Hoveyda, Amir H. | |
| dc.date.accessioned | 2013-11-25T18:03:09Z | |
| dc.date.available | 2013-11-25T18:03:09Z | |
| dc.date.issued | 2011-08 | |
| dc.date.submitted | 2011-05 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/82578 | |
| dc.description.abstract | Monoaryloxide–pyrrolide (MAP) complexes of molybdenum were employed for the selective ethenolysis of 1,2-disubstituted Z olefins in the presence of the corresponding E olefins. Reactions were performed in the presence of 0.02–3.0 mol % catalyst at 22 °C under 20 atm ethylene. We have demonstrated that the Z isomer of an easily accessible E:Z mixture can be destroyed through ethenolysis and the E alkene thereby isolated readily in high yield and exceptional stereoisomeric purity. | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (CHE-0841187) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM-59426) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja205002v | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Marinescu, Smaranda C., Daniel S. Levine, Yu Zhao, Richard R. Schrock, and Amir H. Hoveyda. “Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures.” Journal of the American Chemical Society 133, no. 30 (August 3, 2011): 11512-11514. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Marinescu, Smaranda C. | en_US |
| dc.contributor.mitauthor | Levine, Daniel S. | en_US |
| dc.contributor.mitauthor | Zhao, Yu | en_US |
| dc.contributor.mitauthor | Schrock, Richard Royce | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Marinescu, Smaranda C.; Levine, Daniel S.; Zhao, Yu; Schrock, Richard R.; Hoveyda, Amir H. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0001-5827-3552 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
