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dc.contributor.authorJeong, Hyangsoo
dc.contributor.authorAxtell, Jonathan Clayton
dc.contributor.authorTorok, Bela
dc.contributor.authorSchrock, Richard Royce
dc.contributor.authorMueller, Peter
dc.date.accessioned2014-01-27T13:24:31Z
dc.date.available2014-01-27T13:24:31Z
dc.date.issued2012-08
dc.date.submitted2012-08
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.urihttp://hdl.handle.net/1721.1/84531
dc.description.abstractRoutes to new tungsten alkylidene complexes that contain tert-butylimido or adamantylimido ligands have been devised that begin with a reaction between WCl[subscript 6] and 4 equivalents of HNR(TMS) to give [W(NR)[subscript 2]Cl(μ-Cl)(RNH[subscript 2])][subscript 2] (R = t-Bu or 1-adamantyl). Alkylation leads to W(NR)[subscript 2](CH[subscript 2]R′)[subscript 2] (R′ = t-Bu or CMe[subscript 2]Ph), which upon treatment with pyridinium chloride yields W(NR)(CHR′)Cl[subscript 2](py)[subscript 2] complexes, from which W(NR)(CHR′)(pyrrolide)[subscript 2] and two W(N-t-Bu)(CHR′)(pyrrolide)(OAr) complexes (OAr = hexamethyl- or hexaisopropylterphenoxide) have been prepared.en_US
dc.description.sponsorshipNational Science Foundation (U.S.) (CHE-1111133)en_US
dc.description.sponsorshipNational Science Foundation (U.S.) (Grant CHE-0946721)en_US
dc.language.isoen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/om300799qen_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourceProf. Schrock via Erja Kajosaloen_US
dc.titleSyntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride as the Aciden_US
dc.typeArticleen_US
dc.identifier.citationJeong, Hyangsoo, Jonathan C. Axtell, Bela Torok, Richard R. Schrock, and Peter Mueller. “Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride As the Acid.” Organometallics 31, no. 18 (September 24, 2012): 6522-6525.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.approverSchrock, Richard Royceen_US
dc.contributor.mitauthorJeong, Hyangsooen_US
dc.contributor.mitauthorAxtell, Jonathan Claytonen_US
dc.contributor.mitauthorSchrock, Richard Royceen_US
dc.contributor.mitauthorMueller, Peteren_US
dc.relation.journalOrganometallicsen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsJeong, Hyangsoo; Axtell, Jonathan C.; Torok, Bela; Schrock, Richard R.; Mueller, Peteren_US
dc.identifier.orcidhttps://orcid.org/0000-0002-1788-4100
dc.identifier.orcidhttps://orcid.org/0000-0001-5827-3552
mit.licensePUBLISHER_POLICYen_US
mit.metadata.statusComplete


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