dc.contributor.author | Jeong, Hyangsoo | |
dc.contributor.author | Axtell, Jonathan Clayton | |
dc.contributor.author | Torok, Bela | |
dc.contributor.author | Schrock, Richard Royce | |
dc.contributor.author | Mueller, Peter | |
dc.date.accessioned | 2014-01-27T13:24:31Z | |
dc.date.available | 2014-01-27T13:24:31Z | |
dc.date.issued | 2012-08 | |
dc.date.submitted | 2012-08 | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.issn | 1520-6041 | |
dc.identifier.uri | http://hdl.handle.net/1721.1/84531 | |
dc.description.abstract | Routes to new tungsten alkylidene complexes that contain tert-butylimido or adamantylimido ligands have been devised that begin with a reaction between WCl[subscript 6] and 4 equivalents of HNR(TMS) to give [W(NR)[subscript 2]Cl(μ-Cl)(RNH[subscript 2])][subscript 2] (R = t-Bu or 1-adamantyl). Alkylation leads to W(NR)[subscript 2](CH[subscript 2]R′)[subscript 2] (R′ = t-Bu or CMe[subscript 2]Ph), which upon treatment with pyridinium chloride yields W(NR)(CHR′)Cl[subscript 2](py)[subscript 2] complexes, from which W(NR)(CHR′)(pyrrolide)[subscript 2] and two W(N-t-Bu)(CHR′)(pyrrolide)(OAr) complexes (OAr = hexamethyl- or hexaisopropylterphenoxide) have been prepared. | en_US |
dc.description.sponsorship | National Science Foundation (U.S.) (CHE-1111133) | en_US |
dc.description.sponsorship | National Science Foundation (U.S.) (Grant CHE-0946721) | en_US |
dc.language.iso | en_US | |
dc.publisher | American Chemical Society (ACS) | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1021/om300799q | en_US |
dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
dc.source | Prof. Schrock via Erja Kajosalo | en_US |
dc.title | Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride as the Acid | en_US |
dc.type | Article | en_US |
dc.identifier.citation | Jeong, Hyangsoo, Jonathan C. Axtell, Bela Torok, Richard R. Schrock, and Peter Mueller. “Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride As the Acid.” Organometallics 31, no. 18 (September 24, 2012): 6522-6525. | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
dc.contributor.approver | Schrock, Richard Royce | en_US |
dc.contributor.mitauthor | Jeong, Hyangsoo | en_US |
dc.contributor.mitauthor | Axtell, Jonathan Clayton | en_US |
dc.contributor.mitauthor | Schrock, Richard Royce | en_US |
dc.contributor.mitauthor | Mueller, Peter | en_US |
dc.relation.journal | Organometallics | en_US |
dc.eprint.version | Author's final manuscript | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dspace.orderedauthors | Jeong, Hyangsoo; Axtell, Jonathan C.; Torok, Bela; Schrock, Richard R.; Mueller, Peter | en_US |
dc.identifier.orcid | https://orcid.org/0000-0002-1788-4100 | |
dc.identifier.orcid | https://orcid.org/0000-0001-5827-3552 | |
mit.license | PUBLISHER_POLICY | en_US |
mit.metadata.status | Complete | |