dc.contributor.author | Bonillo Fernandez, Baltasar | |
dc.contributor.author | Swager, Timothy Manning | |
dc.date.accessioned | 2014-01-27T20:10:46Z | |
dc.date.available | 2014-01-27T20:10:46Z | |
dc.date.issued | 2012-11 | |
dc.date.submitted | 2012-08 | |
dc.identifier.issn | 0002-7863 | |
dc.identifier.issn | 1520-5126 | |
dc.identifier.uri | http://hdl.handle.net/1721.1/84605 | |
dc.description.abstract | Lewis acids promote the polymerization of several 2-chloroalkylenedioxythiophenes, providing high-molecular-weight conjugated polymers. The proposed mechanism is a cationic chain-growth polymerization, as confirmed by end-capping reactions and a linear correlation of molecular weight with percent conversion. The “living” character of this process was used to prepare new block copolymers. | en_US |
dc.description.sponsorship | United States. Air Force Office of Scientific Research (FA9550-10-1-0395) | en_US |
dc.language.iso | en_US | |
dc.publisher | American Chemical Society (ACS) | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1021/ja308498h | en_US |
dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
dc.source | Prof. Swager via Erja Kajosalo | en_US |
dc.title | Chain-Growth Polymerization of 2-Chlorothiophenes Promoted by Lewis Acids | en_US |
dc.type | Article | en_US |
dc.identifier.citation | Bonillo, Baltasar, and Timothy M. Swager. “Chain-Growth Polymerization of 2-Chlorothiophenes Promoted by Lewis Acids.” Journal of the American Chemical Society 134, no. 46 (November 21, 2012): 18916-18919. | en_US |
dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
dc.contributor.approver | Swager, Timothy M. | en_US |
dc.contributor.mitauthor | Bonillo Fernandez, Baltasar | en_US |
dc.contributor.mitauthor | Swager, Timothy Manning | en_US |
dc.relation.journal | Journal of the American Chemical Society | en_US |
dc.eprint.version | Author's final manuscript | en_US |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
dspace.orderedauthors | Bonillo, Baltasar; Swager, Timothy M. | en_US |
mit.license | PUBLISHER_POLICY | en_US |
mit.metadata.status | Complete | |