| dc.contributor.author | Pluth, Michael D. | |
| dc.contributor.author | Lippard, Stephen J. | |
| dc.date.accessioned | 2014-01-31T16:54:04Z | |
| dc.date.available | 2014-01-31T16:54:04Z | |
| dc.date.issued | 2012-10 | |
| dc.date.submitted | 2012-10 | |
| dc.identifier.issn | 1359-7345 | |
| dc.identifier.issn | 1364-548X | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/84620 | |
| dc.description.abstract | Nitric oxide binds reversibly to the Fe(III) complex of a well-developed tetra-amido macrocyclic ligand. Reaction with NO results in formation of a species consistent with an S = 1 {Fe–NO}[superscript 6] ground state as characterized by UV-vis, IR, EPR, and Mössbauer spectroscopy. The resultant nitrosyl is labile and dissociates readily upon purging with N[subscript 2], thus providing a rare example of reversible NO binding to non-heme iron. | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (CHE-061194) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (K99GM092970) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1039/c2cc37221e | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
| dc.source | PMC | en_US |
| dc.title | Reversible binding of nitric oxide to an Fe(iii) complex of a tetra-amido macrocycle | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Pluth, Michael D., and Stephen J. Lippard. “Reversible binding of nitric oxide to an Fe(iii) complex of a tetra-amido macrocycle.” Chemical Communications 48, no. 98 (2012): 11981. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Pluth, Michael D. | en_US |
| dc.contributor.mitauthor | Lippard, Stephen J. | en_US |
| dc.relation.journal | Chemical Communications | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Pluth, Michael D.; Lippard, Stephen J. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0002-2693-4982 | |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
