Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5)

Author(s)
Royappa, A. Timothy; Stepherson, Jacob R.; Vu, Oliver D.; Royappa, Andrew D.; Stern, Charlotte L.; ... Show more
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Abstract
In the title compound, [Cu(CH[subscript 3]CN)[subscript 4]](C[subscript 2]HO[subscript 4])·0.5C[subscript 2]H[subscript 2]O[subscript 4]·0.5CH[subscript 3]CN, the Cu[superscript I] ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxalic acid molecule lies across an inversion center. The acetonitrile solvent molecule is disordered across an inversion center and was refined with half occupancy. In the crystal, the hydrogen oxalate anions and oxalic acid molecules are linked via O-H...O hydrogen bonds, forming chains along [010].
Date issued
2013-09
URI
http://hdl.handle.net/1721.1/89419
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Acta Crystallographica Section E Structure Reports Online
Citation
Royappa, A. Timothy, Jacob R. Stepherson, Oliver D. Vu, Andrew D. Royappa, Charlotte L. Stern, and Peter Müller. “Tetrakis(acetonitrile)copper(I) Hydrogen Oxalate–oxalic Acid–acetonitrile (1/0.5/0.5).” Acta Cryst E 69, no. 10 (September 18, 2013): m544–m544.
Version: Final published version
ISSN
1600-5368
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