Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

Author(s)
Yang, Yang; Buchwald, Stephen Leffler
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Abstract
An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product.
Date issued
2013-07
URI
http://hdl.handle.net/1721.1/93917
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Yang, Yang, and Stephen L. Buchwald. “Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides.” Journal of the American Chemical Society 135, no. 29 (July 24, 2013): 10642–10645.
Version: Author's final manuscript
ISSN
0002-7863
1520-5126
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