| dc.contributor.author | Spokoyny, Alexander M. | |
| dc.contributor.author | Lewis, Calvin D. | |
| dc.contributor.author | Teverovskiy, Georgiy | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2015-02-06T20:19:04Z | |
| dc.date.available | 2015-02-06T20:19:04Z | |
| dc.date.issued | 2012-11 | |
| dc.date.submitted | 2012-11 | |
| dc.identifier.issn | 0276-7333 | |
| dc.identifier.issn | 1520-6041 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/93919 | |
| dc.description.abstract | We have prepared the first examples of B9-connected trivalent aryl and alkyl phosphinoborane species via Pd-catalyzed phosphination of 9-iodo-meta-carborane. Our studies highlight the unique electronic features of the B9-connected meta-carboranyl moiety as compared to its C1-based analogue. This work suggests that the B9-functionalized meta-carboranyl substituent in these ligands exhibits more electron-releasing character than any other known carbon-based substituent, ultimately laying the foundation for a new class of phosphine ligands with extremely electron-rich character. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM46059) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Fellowship 1F32GM101762) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/om301116x | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Spokoyny, Alexander M., Calvin D. Lewis, Georgiy Teverovskiy, and Stephen L. Buchwald. “Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes.” Organometallics 31, no. 24 (December 24, 2012): 8478–8481. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Spokoyny, Alexander M. | en_US |
| dc.contributor.mitauthor | Lewis, Calvin D. | en_US |
| dc.contributor.mitauthor | Teverovskiy, Georgiy | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.relation.journal | Organometallics | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Spokoyny, Alexander M.; Lewis, Calvin D.; Teverovskiy, Georgiy; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
