| dc.contributor.author | Yang, Yang | |
| dc.contributor.author | Oldenhuis, Nathan J. | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2015-02-06T20:35:11Z | |
| dc.date.available | 2015-02-06T20:35:11Z | |
| dc.date.issued | 2012-11 | |
| dc.date.submitted | 2012-09 | |
| dc.identifier.issn | 14337851 | |
| dc.identifier.issn | 1521-3773 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/93921 | |
| dc.description.abstract | A wide range of biaryls were synthesized by palladium-catalyzed Negishi cross-couplings at ambient temperature or with low catalyst loading. This protocol features the use of a recently reported aminobiphenyl palladacycle precatalyst to generate the catalytically active XPhosPd[superscript 0] species. Significantly, a wide range of challenging heterocyclic and polyfluorinated aromatic substrates can be employed to give products in excellent yields. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM46059) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Wiley Blackwell | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1002/anie.201207750 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | en_US |
| dc.source | PMC | en_US |
| dc.title | Mild and General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Yang, Yang, Nathan J. Oldenhuis, and Stephen L. Buchwald. “Mild and General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts.” Angewandte Chemie International Edition 52, no. 2 (November 22, 2012): 615–619. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Yang, Yang | en_US |
| dc.contributor.mitauthor | Oldenhuis, Nathan J. | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.relation.journal | Angewandte Chemie International Edition | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Yang, Yang; Oldenhuis, Nathan J.; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
