| dc.contributor.author | Michaelis, Vladimir K. | |
| dc.contributor.author | Smith, Albert A. | |
| dc.contributor.author | Haze, Olesya | |
| dc.contributor.author | Corzilius, Bjorn | |
| dc.contributor.author | Griffin, Robert Guy | |
| dc.contributor.author | Swager, Timothy M | |
| dc.date.accessioned | 2015-02-18T21:40:20Z | |
| dc.date.available | 2015-02-18T21:40:20Z | |
| dc.date.issued | 2013-02 | |
| dc.date.submitted | 2012-12 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/94625 | |
| dc.description.abstract | We report direct [superscript 13]C dynamic nuclear polarization at 5 T under magic-angle spinning (MAS) at 82 K using a mixture of monoradicals with narrow EPR linewidths. We show the importance of optimizing both EPR linewidth and electron relaxation times by studying direct DNP of [superscript 13]C using SA-BDPA and trityl radical, and achieve [superscript 13]C enhancements above 600. This new approach may be best suited for dissolution DNP and for studies of [superscript 1]H depleted biological and other nonprotonated solids. | en_US |
| dc.description.sponsorship | National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Grant EB-002804) | en_US |
| dc.description.sponsorship | National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Grant EB-002026) | en_US |
| dc.description.sponsorship | National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Grant EB-001960) | en_US |
| dc.description.sponsorship | National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Grant GM-095843)) | en_US |
| dc.description.sponsorship | Natural Sciences and Engineering Research Council of Canada (Postdoctoral Fellowship) | en_US |
| dc.description.sponsorship | German Science Foundation (Research Fellowship CO 802/1-1) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja312265x | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | High-Field [superscript 13] C Dynamic Nuclear Polarization with a Radical Mixture | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Michaelis, Vladimir K., Albert A. Smith, Bjorn Corzilius, Olesya Haze, Timothy M. Swager, and Robert G. Griffin. “High-Field [superscript 13] C Dynamic Nuclear Polarization with a Radical Mixture.” Journal of the American Chemical Society 135, no. 8 (February 27, 2013): 2935–2938. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.department | Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) | en_US |
| dc.contributor.mitauthor | Michaelis, Vladimir K. | en_US |
| dc.contributor.mitauthor | Smith, Albert A. | en_US |
| dc.contributor.mitauthor | Corzilius, Bjorn | en_US |
| dc.contributor.mitauthor | Haze, Olesya | en_US |
| dc.contributor.mitauthor | Swager, Timothy Manning | en_US |
| dc.contributor.mitauthor | Griffin, Robert Guy | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Michaelis, Vladimir K.; Smith, Albert A.; Corzilius, Bjorn; Haze, Olesya; Swager, Timothy M.; Griffin, Robert G. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-1589-832X | |
| dc.identifier.orcid | https://orcid.org/0000-0002-6708-7660 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
