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dc.contributor.authorSmith, Stacey J.
dc.contributor.authorJamison, Timothy F.
dc.contributor.authorStandley, Eric
dc.contributor.authorMueller, Peter
dc.date.accessioned2015-06-22T13:57:09Z
dc.date.available2015-06-22T13:57:09Z
dc.date.issued2014-04
dc.date.submitted2014-02
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.urihttp://hdl.handle.net/1721.1/97490
dc.description.abstractA series of air-stable nickel complexes of the form L[subscript 2]Ni(aryl) X (L = monodentate phosphine, X = Cl, Br) and LNi(aryl)X (L = bis-phosphine) have been synthesized and are presented as a library of precatalysts suitable for a wide variety of nickel-catalyzed transformations. These complexes are easily synthesized from low-cost NiCl[subscript 2]·6H[subscript 2]O or NiBr[subscript 2]·3H[subscript 2]O and the desired ligand followed by addition of 1 equiv of Grignard reagent. A selection of these complexes were characterized by single-crystal X-ray diffraction, and an analysis of their structural features is provided. A case study of their use as precatalysts for the nickel-catalyzed carbonyl-ene reaction is presented, showing superior reactivity in comparison to reactions using Ni(cod)[subscript 2]. Furthermore, as the precatalysts are all stable to air, no glovebox or inert-atmosphere techniques are required to make use of these complexes for nickel-catalyzed reactions.en_US
dc.description.sponsorshipNational Institute of General Medical Sciences (U.S.) (GM63755)en_US
dc.description.sponsorshipNational Science Foundation (U.S.). Graduate Research Fellowshipen_US
dc.language.isoen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/om500156qen_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourceAmerican Chemical Societyen_US
dc.titleA Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexesen_US
dc.typeArticleen_US
dc.identifier.citationStandley, Eric A., Stacey J. Smith, Peter Müller, and Timothy F. Jamison. “A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes.” Organometallics 33, no. 8 (April 28, 2014): 2012–2018. © 2014 American Chemical Societyen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.mitauthorStandley, Ericen_US
dc.contributor.mitauthorSmith, Stacey J.en_US
dc.contributor.mitauthorMueller, Peteren_US
dc.contributor.mitauthorJamison, Timothy F.en_US
dc.relation.journalOrganometallicsen_US
dc.eprint.versionFinal published versionen_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsStandley, Eric A.; Smith, Stacey J.; Müller, Peter; Jamison, Timothy F.en_US
dc.identifier.orcidhttps://orcid.org/0000-0002-8601-7799
mit.licensePUBLISHER_POLICYen_US
mit.metadata.statusComplete


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