Dimerization of functional pyrroloindolizines for the synthesis of complex myrmicarin alkaloids

Author(s)
Ondrus, Alison E.; Kaniskan, Husnu Umit; Movassaghi, Mohammad
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Abstract
The union of functionalized pyrroloindolizines for the synthesis of heterodimeric products relevant to myrmicarin alkaloids is described. Design and synthesis of tricyclic substrates and new methods for their union enable the investigation of late-stage cyclopentannulation strategies. The rapid assembly of dimeric structures using unique modes of pyrroloindolizine reactivity presents a concise approach to the dimeric myrmicarins and relevant derivatives.
Date issued
2010-04
URI
http://hdl.handle.net/1721.1/71196
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Tetrahedron
Publisher
Elsevier B.V.
Citation
Ondrus, Alison E., H. Ümit Kaniskan, and Mohammad Movassaghi. “Dimerization of Functional Pyrroloindolizines for the Synthesis of Complex Myrmicarin Alkaloids.” Tetrahedron 66.26 (2010): 4784–4795. Web.
Version: Author's final manuscript
ISSN
0040-4020
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