| dc.contributor.author | Ueda, Satoshi | |
| dc.contributor.author | Fors, Brett P. | |
| dc.contributor.author | Ali, Siraj Z. | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2013-11-04T14:04:14Z | |
| dc.date.available | 2013-11-04T14:04:14Z | |
| dc.date.issued | 2012-02 | |
| dc.date.submitted | 2011-12 | |
| dc.identifier.issn | 0022-3263 | |
| dc.identifier.issn | 1520-6904 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/81960 | |
| dc.description.abstract | A new biarylphosphine ligand, Me[subscript 3](OMe)tBuXPhos (L3), was designed as a surrogate for Me[subscript 4]tBuXPhos (L1). The Me[subscript 3](OMe)tBuXPhos could be prepared in a chromatography-free manner from inexpensive and readily available 2,3,6-trimethylphenol. Comparative studies demonstrated that a catalyst based on Me[subscript 3](OMe)tBuXPhos displayed the same reactivity as a catalyst based on Me[subscript 4]tBuXPhos for Pd-catalyzed C–N and C–O bond-forming processes. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM58160) | en_US |
| dc.description.sponsorship | Massachusetts Institute of Technology. Undergraduate Research Opportunities Program | en_US |
| dc.description.sponsorship | Bristol-Myers Squibb Company (Graduate Fellowship) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/jo202537e | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Me[subscript 3](OMe)tBuXPhos: A Surrogate Ligand for Me[subscript 4]tBuXPhos in Palladium-Catalyzed C-N and C-O Bond-Forming Reactions | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Ueda, Satoshi, Siraj Ali, Brett P. Fors, and Stephen L. Buchwald. “Me3(OMe)tBuXPhos: A Surrogate Ligand for Me4tBuXPhos in Palladium-Catalyzed C–N and C–O Bond-Forming Reactions.” The Journal of Organic Chemistry 77, no. 5 (March 2, 2012): 2543-2547. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Ueda, Satoshi | en_US |
| dc.contributor.mitauthor | Ali, Siraj Z. | en_US |
| dc.contributor.mitauthor | Fors, Brett P. | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.relation.journal | The Journal of Organic Chemistry | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Ueda, Satoshi; Ali, Siraj; Fors, Brett P.; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
