| dc.contributor.author | Yang, Dengtao | |
| dc.contributor.author | Zhu, Minghui | |
| dc.contributor.author | Schiffer, Zachary J. | |
| dc.contributor.author | Williams, Kindle | |
| dc.contributor.author | Song, Xiaojie | |
| dc.contributor.author | Liu, Xiaohui | |
| dc.contributor.author | Manthiram, Karthish | |
| dc.date.accessioned | 2020-06-12T20:40:14Z | |
| dc.date.available | 2020-06-12T20:40:14Z | |
| dc.date.issued | 2019-04 | |
| dc.date.submitted | 2019-04 | |
| dc.identifier.issn | 2155-5435 | |
| dc.identifier.uri | https://hdl.handle.net/1721.1/125787 | |
| dc.description.abstract | We report a direct and efficient electrochemical carboxylation of benzylic C-N bonds with CO₂ at room temperature. The reaction has been successfully applied to both primary and secondary benzylic C-N bonds with the compatibility of a variety of functional groups. This procedure does not require stoichiometric metals, external reducing agents, or sacrificial anodes, making column chromatography unnecessary for product purification. Differential electrochemical mass spectrometry (DEMS) was used to elucidate key intermediates of the electrocarboxylation reaction. | en_US |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/acscatal.9b00818 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | Prof. Manthiram via Ye Li | en_US |
| dc.title | Direct Electrochemical Carboxylation of Benzylic C–N Bonds with Carbon Dioxide | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Yang, Deng-Tao et al. "Direct Electrochemical Carboxylation of Benzylic C–N Bonds with Carbon Dioxide." ACS Catalysis 9, 5 (April 2019): 4699–4705 © 2019 American Chemical Society | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemical Engineering | en_US |
| dc.relation.journal | ACS Catalysis | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dc.date.updated | 2020-06-08T14:56:00Z | |
| dspace.date.submission | 2020-06-08T14:56:02Z | |
| mit.journal.volume | 9 | en_US |
| mit.journal.issue | 5 | en_US |
| mit.license | PUBLISHER_POLICY | |
| mit.metadata.status | Complete | |
