Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions
Author(s)Strieth-Kalthoff, Felix; Longstreet, Ashley R.; Weber, Jessica Marie; Jamison, Timothy F
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Herein, we introduce a new class of bench-stable N-heterocyclic carbene (NHC) nickel-precatalysts for homogeneous nickel-catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck-type mechanism. The precatalysts are shown to facilitate carbonyl-ene, hydroalkenylation, and amination reactions.
DepartmentMassachusetts Institute of Technology. Department of Chemistry
Strieth-Kalthoff, Felix, et al., "Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions." ChemCatChem 10, 13 (July 2018): p. 2873-77 doi 10.1002/CCTC.201800454 ©2018 Author(s)
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