Unexpected Formation of Hexasubstituted Arenes through a 2-fold Palladium-Mediated Ligand Arylation
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© 2019 American Chemical Society. A rearrangement reaction of biarylphosphine-supported Pd(II) complexes was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene compounds, a class of molecules that has not previously been reported. The strain of the central hexasubstituted ring was investigated via X-ray crystallography.
Date issued
2019Department
Massachusetts Institute of Technology. Department of ChemistryJournal
Journal of Organic Chemistry
Publisher
American Chemical Society (ACS)