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Amphiphilic Biaryl Monophosphine Ligands by Regioselective Sulfonation
| dc.contributor.author | Rodriguez, Jacob | |
| dc.contributor.author | Dhanjee, Heemal H | |
| dc.contributor.author | Buchwald, Stephen L | |
| dc.date.accessioned | 2022-02-14T19:07:38Z | |
| dc.date.available | 2022-02-14T19:07:38Z | |
| dc.date.issued | 2021 | |
| dc.identifier.uri | https://hdl.handle.net/1721.1/140333 | |
| dc.description.abstract | © 2021 American Chemical Society. Amphiphilic ligands are valued for their ability to facilitate organometallic reactions in the presence of water. The regioselective sulfonation of a series of commercially available biaryl monophosphines to generate amphiphilic ligands is presented. In this one-step protocol, the temperature and addition of fuming sulfuric acid were carefully controlled to arrive at sulfonated biaryl monophosphine ligands in high yields with >95% regioselectivity without the need for chromatographic purification. | en_US |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | 10.1021/ACS.ORGLETT.0C04001 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | en_US |
| dc.source | PMC | en_US |
| dc.title | Amphiphilic Biaryl Monophosphine Ligands by Regioselective Sulfonation | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Rodriguez, Jacob, Dhanjee, Heemal H and Buchwald, Stephen L. 2021. "Amphiphilic Biaryl Monophosphine Ligands by Regioselective Sulfonation." Organic Letters, 23 (3). | |
| dc.relation.journal | Organic Letters | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dc.date.updated | 2022-02-14T18:52:34Z | |
| dspace.orderedauthors | Rodriguez, J; Dhanjee, HH; Buchwald, SL | en_US |
| dspace.date.submission | 2022-02-14T18:52:36Z | |
| mit.journal.volume | 23 | en_US |
| mit.journal.issue | 3 | en_US |
| mit.license | OPEN_ACCESS_POLICY | |
| mit.metadata.status | Authority Work and Publication Information Needed | en_US |
