Thermal Cycling of a MOF-Based NO Disproportionation Catalyst
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© 2021 American Chemical Society. The metal-organic framework CuI-MFU-4l reacts with NO, initially forming a copper(I)-nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII-NO2 and N2O. The thermal stability of MFU-4l allows NOx to be released from the framework at temperatures greater than 200 °C. This treatment regenerates the original CuI-MFU-4l, which can engage in subsequent cycles of NO disproportionation.
Date issued
2021-01Department
Massachusetts Institute of Technology. Department of ChemistryJournal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Wright, Ashley M, Sun, Chenyue and Dincă, Mircea. 2021. "Thermal Cycling of a MOF-Based NO Disproportionation Catalyst." Journal of the American Chemical Society, 143 (2).
Version: Author's final manuscript
ISSN
0002-7863
1520-5126