| dc.contributor.author | Dinakar, Bhavish | |
| dc.contributor.author | Oppenheim, Julius J | |
| dc.contributor.author | Vandone, Marco | |
| dc.contributor.author | Torres, Juan F | |
| dc.contributor.author | Iliescu, Andrei | |
| dc.contributor.author | Yang, Zhentao | |
| dc.contributor.author | Román-Leshkov, Yuriy | |
| dc.contributor.author | Dincă, Mircea | |
| dc.date.accessioned | 2025-11-25T21:12:08Z | |
| dc.date.available | 2025-11-25T21:12:08Z | |
| dc.date.issued | 2025-08-14 | |
| dc.identifier.uri | https://hdl.handle.net/1721.1/164069 | |
| dc.description.abstract | Here, we report an intrinsically disordered MOF in the MOF-74 family,
Mg2x(as-dobpdc) (as-dobpdc4 = 30
,4-dioxidobiphenyl-3,40
-dicarboxylate). Despite the absence of crystallinity, this material exhibits
local ordering consistent with that of its crystalline isomers, maintains
porosity, and exhibits a high density of open metal sites. | en_US |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.relation.isversionof | 10.1039/d5cc03713a | en_US |
| dc.rights | Creative Commons Attribution | en_US |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en_US |
| dc.source | Royal Society of Chemistry | en_US |
| dc.title | Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Dinakar, Bhavish, Oppenheim, Julius J, Vandone, Marco, Torres, Juan F, Iliescu, Andrei et al. 2025. "Asymmetric linker generates intrinsically disordered metal–organic framework with local MOF-74 structure." Chemical Communications, 61 (67). | |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemical Engineering | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.relation.journal | Chemical Communications | en_US |
| dc.eprint.version | Final published version | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dc.date.updated | 2025-11-25T20:57:37Z | |
| dspace.orderedauthors | Dinakar, B; Oppenheim, JJ; Vandone, M; Torres, JF; Iliescu, A; Yang, Z; Román-Leshkov, Y; Dincă, M | en_US |
| dspace.date.submission | 2025-11-25T20:57:38Z | |
| mit.journal.volume | 61 | en_US |
| mit.journal.issue | 67 | en_US |
| mit.license | PUBLISHER_CC | |
| mit.metadata.status | Authority Work and Publication Information Needed | en_US |
