| dc.contributor.author | Tomat, Elisa | |
| dc.contributor.author | Lippard, Stephen J. | |
| dc.date.accessioned | 2011-12-15T18:42:01Z | |
| dc.date.available | 2011-12-15T18:42:01Z | |
| dc.date.issued | 2010-09 | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.issn | 1520-510X | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/67697 | |
| dc.description | Synthetic procedures and product characterization data, zinc binding analysis methods, selectivity and pH dependence charts. This material is available free of charge via the Internet at http://pubs.acs.edu. | en_US |
| dc.description.abstract | A xanthene-forming condensation reaction yields rhodol and rhodamine dyes carrying a zinc-binding ligand that includes the aniline-type nitrogen donor of the fluorophores. Upon zinc coordination in neutral aqueous solution, rhodol RF3 behaves as a ratiometric sensor, and rhodamine RA1 acts as a turn-off intensity-based indicator. Both fluorescent compounds bind the divalent zinc cation with micromolar affinity. | en_US |
| dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (grant GM065519) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ic101513a | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | Prof. Lippard via Erja Kajosalo | en_US |
| dc.title | Ratiometric and intensity-based zinc sensors built on rhodol and rhodamine platforms | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Tomat, Elisa, and Stephen J. Lippard. “Ratiometric and Intensity-Based Zinc Sensors Built on Rhodol and Rhodamine Platforms.” Inorganic Chemistry 49 (2010): 9113-9115. Web. 15 Dec. 2011. © 2011 American Chemical Society | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.approver | Lippard, Stephen J. | |
| dc.contributor.mitauthor | Tomat, Elisa | |
| dc.contributor.mitauthor | Lippard, Stephen J. | |
| dc.relation.journal | Inorganic Chemistry | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Tomat, Elisa; Lippard, Stephen J. | en |
| dc.identifier.orcid | https://orcid.org/0000-0002-2693-4982 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
