Characterization of a synthetic peroxodiiron(III) protein model complex by nuclear resonance vibrational spectroscopy

Author(s)
Do, Loi Hung; Wang, Hongxin; Tinberg, Christine E.; Dowty, Eric; Yoda, Yoshitaka; ... Show more
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Abstract
The vibrational spectrum of an η[superscript 1],η[superscript 1]-1,2-peroxodiiron(III) complex was measured by nuclear resonance vibrational spectroscopy and fit using an empirical force field analysis. Isotopic 18O2 labelling studies revealed a feature involving motion of the {Fe2(O2)}[superscript 4+] core that was not previously observed by resonance Raman spectroscopy.
Date issued
2011-09
URI
http://hdl.handle.net/1721.1/74053
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Chemical Communications
Publisher
Royal Society of Chemistry, The
Citation
Do, Loi H. et al. “Characterization of a Synthetic Peroxodiiron(iii) Protein Model Complex by Nuclear Resonance Vibrational Spectroscopy.” Chemical Communications 47.39 (2011): 10945.
Version: Author's final manuscript
ISSN
1359-7345
1364-548X
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