| dc.contributor.author | Matsuki, Yoh | |
| dc.contributor.author | Maly, Thorsten | |
| dc.contributor.author | Ouari, Olivier | |
| dc.contributor.author | Karoui, Hakim | |
| dc.contributor.author | Le Moigne, Francois | |
| dc.contributor.author | Rizzato, Egon | |
| dc.contributor.author | Lyubenova, Sevdalina | |
| dc.contributor.author | Herzfeld, Judith | |
| dc.contributor.author | Prisner, Thomas | |
| dc.contributor.author | Tordo, Paul | |
| dc.contributor.author | Griffin, Robert Guy | |
| dc.date.accessioned | 2012-10-24T18:42:30Z | |
| dc.date.available | 2012-10-24T18:42:30Z | |
| dc.date.issued | 2009-06 | |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.issn | 1521-3773 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/74234 | |
| dc.description.abstract | A new polarizing agent with superior performance in dynamic nuclear polarization experiments is introduced, and utilizes two TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) moieties connected through a rigid spiro tether (see structure). The observed NMR signal intensities were enhanced by a factor of 1.4 compared to those of TOTAPOL, a previously described TEMPO-based biradical with a flexible tether. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (EB002804) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (EB002026) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (EB009866) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (EB001965) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (EB001035) | en_US |
| dc.description.sponsorship | Sixth Framework Programme (European Commission) (EU-Design Study Bio-DNP) | en_US |
| dc.description.sponsorship | Deutsche Forschungsgemeinschaft (postdoctoral fellowship) | en_US |
| dc.description.sponsorship | Naito Foundation | en_US |
| dc.language.iso | en_US | |
| dc.publisher | John Wiley & Sons, Inc. | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1002/anie.200805940 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
| dc.source | Prof. Swager via Erja Kajosalo | en_US |
| dc.title | Dynamic nuclear polarization with a rigid biradical | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Matsuki, Yoh et al. “Dynamic Nuclear Polarization with a Rigid Biradical.” Angewandte Chemie International Edition 48.27 (2009): 4996–5000. Web. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.department | Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) | en_US |
| dc.contributor.approver | Swager, Timothy Manning | |
| dc.contributor.mitauthor | Swager, Timothy Manning | |
| dc.contributor.mitauthor | Griffin, Robert Guy | |
| dc.contributor.mitauthor | Maly, Thorsten | |
| dc.relation.journal | Angewandte Chemie International Edition | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Matsuki, Yoh; Maly, Thorsten; Ouari, Olivier; Karoui, Hakim; Le Moigne, François; Rizzato, Egon; Lyubenova, Sevdalina; Herzfeld, Judith; Prisner, Thomas; Tordo, Paul; Griffin, Robert G. | en |
| dc.identifier.orcid | https://orcid.org/0000-0003-1589-832X | |
| dspace.mitauthor.error | true | |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
