| dc.contributor.author | Shen, Xiaoqiang | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2013-11-01T15:04:16Z | |
| dc.date.available | 2013-11-01T15:04:16Z | |
| dc.date.issued | 2009-12 | |
| dc.date.submitted | 2009-11 | |
| dc.identifier.issn | 14337851 | |
| dc.identifier.issn | 1521-3773 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/81938 | |
| dc.description.abstract | One for the Rh(oad): The first rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated olefins was developed by using dialkylbiaryl phosphine ligands (see scheme; cod=1,5-cyclooctadiene, Cy=cyclohexyl). A variety of 2-methylpyrrolidines have been synthesized with high enantioselectivities. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant GM46059) | en_US |
| dc.description.sponsorship | Merck & Co. | en_US |
| dc.description.sponsorship | Boehringer Ingelheim Pharmaceuticals | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM 1S10RR13886-01) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Wiley Blackwell | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1002/anie.200905402 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
| dc.source | PMC | en_US |
| dc.title | Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Shen, Xiaoqiang, and Stephen L. Buchwald. “Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes.” Angewandte Chemie International Edition 49, no. 3 (January 12, 2010): 564-567. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Shen, Xiaoqiang | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.relation.journal | Angewandte Chemie International Edition | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Shen, Xiaoqiang; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
