| dc.contributor.author | Rousseaux, Sophie | |
| dc.contributor.author | Garcia-Fortanet, Jorge | |
| dc.contributor.author | Del Aguila Sanchez, Miguel Angel | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2013-11-01T15:34:06Z | |
| dc.date.available | 2013-11-01T15:34:06Z | |
| dc.date.issued | 2011-05 | |
| dc.date.submitted | 2011-04 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/81941 | |
| dc.description.abstract | The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee). | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant GM46059) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (Grant CHE 9808061) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (Grant DBI 9729592) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja203644q | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Palladium(0)-Catalyzed Arylative Dearomatization of Phenols | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Rousseaux, Sophie, Jorge Garcia-Fortanet, Miguel Angel Del Aguila Sanchez, and Stephen L. Buchwald. “Palladium(0)-Catalyzed Arylative Dearomatization of Phenols.” Journal of the American Chemical Society 133, no. 24 (June 22, 2011): 9282-9285. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.contributor.mitauthor | Rousseaux, Sophie | en_US |
| dc.contributor.mitauthor | Garcia-Fortanet, Jorge | en_US |
| dc.contributor.mitauthor | Del Aguila Sanchez, Miguel Angel | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Rousseaux, Sophie; Garcia-Fortanet, Jorge; Del Aguila Sanchez, Miguel Angel; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| dspace.mitauthor.error | true | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
