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dc.contributor.authorParsons, Andrew T.
dc.contributor.authorSenecal, Todd D.
dc.contributor.authorBuchwald, Stephen Leffler
dc.date.accessioned2013-11-01T15:56:26Z
dc.date.available2013-11-01T15:56:26Z
dc.date.issued2012-02
dc.date.submitted2011-11
dc.identifier.issn14337851
dc.identifier.issn1521-3773
dc.identifier.urihttp://hdl.handle.net/1721.1/81943
dc.description.abstractExchanging BF[subscript 3] by CF[subscript 3]: The title reaction proceeds under exceedingly mild reaction conditions and provides 2-arylvinyl- and 2-heteroarylvinyl-substituted substrates with E/Z selectivities of more than 95:5. Experimental observations suggest that the reaction does not proceed through a transmetalation of the RBF[subscript 3]K species to the iron catalyst.en_US
dc.description.sponsorshipNational Institutes of Health (U.S.) (Grant GM46059)en_US
dc.description.sponsorshipNational Institutes of Health (U.S.) (Postdoctoral Fellowship F32M093532)en_US
dc.description.sponsorshipNational Science Foundation (U.S.) (Grant CHE-9808061)en_US
dc.description.sponsorshipNational Science Foundation (U.S.) (Grant DBI-9729592)en_US
dc.description.sponsorshipNational Institutes of Health (U.S.) (Grant 1S10RR13886-01)en_US
dc.language.isoen_US
dc.publisherWiley Blackwellen_US
dc.relation.isversionofhttp://dx.doi.org/10.1002/anie.201108267en_US
dc.rightsCreative Commons Attribution-Noncommercial-Share Alike 3.0en_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-sa/3.0/en_US
dc.sourcePMCen_US
dc.titleIron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroboratesen_US
dc.typeArticleen_US
dc.identifier.citationParsons, Andrew T., Todd D. Senecal, and Stephen L. Buchwald. “Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates.” Angewandte Chemie International Edition 51, no. 12 (March 19, 2012): 2947-2950.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.mitauthorParsons, Andrew T.en_US
dc.contributor.mitauthorSenecal, Todd D.en_US
dc.contributor.mitauthorBuchwald, Stephen Leffleren_US
dc.relation.journalAngewandte Chemie International Editionen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsParsons, Andrew T.; Senecal, Todd D.; Buchwald, Stephen L.en_US
dc.identifier.orcidhttps://orcid.org/0000-0003-3875-4775
mit.licenseOPEN_ACCESS_POLICYen_US
mit.metadata.statusComplete


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